Synthesis, characterization, and crystal structure of aquabis(4,4′-dimethoxy-2,2′-bipyridine)[μ-(2𝘙,3𝘙)-tartrato(4−)]dicopper(II) octahydrate

Abstract

Typical electroless copper baths (ECBs), which are used to chemically deposit copper on printed circuit boards, consist of an aqueous alkali hydroxide solution, a copper(II) salt, formaldehyde as reducing agent, an l-(+)-tartrate as complexing agent, and a 2,2′-bipyridine derivative as stabilizer. Actual speciation and reactivity are, however, largely unknown. Herein, we report on the synthesis and crystal structure of aqua-1κO-bis(4,4′-dimethoxy-2,2′-bipyridine)-1κ²N,N′;2κ²N,N′-[μ-(2R,3R)-2,3-dioxidosuccinato-1κ²O²,O²:2κ²O²,O²]dicopper(II) octahydrate, [Cu₂(C₁₂H₁₂N₂O₂)₂(C₄H₂O₆)(H₂O)] · 8 H₂O, from an ECB mock-up. The title compound crystallizes in the Sohncke group P2₁ with one chiral dinuclear complex and eight mol­ecules of hydrate water in the asymmetric unit. The expected retention of the tartrato ligand’s absolute configuration was confirmed via determination of the absolute structure. The complex molecules exhibit an ansa-like structure with two planar, nearly parallel bi­pyridine ligands, each bound to a copper atom that is connected to the other by a bridging tartrato ‘handle’. The complex and water molecules give rise to a layered supramolecular structure dominated by alternating π stacks and hydrogen bonds. The understanding of structures ex situ is a first step on the way to prolonged stability and improved coating behavior of ECBs.

Dr. Dennis Wiedemann

Technischer Berater für Umweltfragen
Chemiker · Kristallograph

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